Extraction of the trivalent transplutonium actinides americium through einsteinium by the sulfur donor Cyanex 301-Reference-Cited by-同舟云学术

Extraction of the trivalent transplutonium actinides americium through einsteinium by the sulfur donor Cyanex 301

Published:2021 Issue:18 Volume:8 Page:4177-4185
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Bessen Nathan¹^ORCID,Yan Qiang²^ORCID,Pu Ning²,Chen Jing²,Xu Chao²^ORCID,Shafer Jenifer¹^ORCID

Affiliation:

1. Colorado School of Mines, 1500 Illinois St, Golden, CO 80401, USA

2. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

Abstract

When extracting metals with the sulfur donor ligand, Cyanex 301 (bis(2,4,4-trimethylpentyl)dithiophosphinic acid), a transition in the coordination mode of extracted complexes has been observed between Eu and Gd, but not within the actinide series.

Funder

Basic Energy Sciences

Natural Science Foundation of Beijing Municipality

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QI/D1QI00076D

Reference46 articles.

1. Synthesis of symmetric dithiophosphinic acids for “minor actinide” extraction

2. Selective Extraction of Minor Actinides from Acidic Media Using Symmetric and Asymmetric Dithiophosphinic Acids

3. Extraction of Am(III) and Eu(III) from Nitrate Solution with Purified Cyanex 301

4. Sulfur donating extractants for the separation of trivalent actinides and lanthanides

5. Influence of aggregation on the extraction of trivalent lanthanide and actinide cations by purified Cyanex 272, Cyanex 301, and Cyanex 302

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