Extraction of the trivalent transplutonium actinides americium through einsteinium by the sulfur donor Cyanex 301

Author:

Bessen Nathan1ORCID,Yan Qiang2ORCID,Pu Ning2,Chen Jing2,Xu Chao2ORCID,Shafer Jenifer1ORCID

Affiliation:

1. Colorado School of Mines, 1500 Illinois St, Golden, CO 80401, USA

2. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

Abstract

When extracting metals with the sulfur donor ligand, Cyanex 301 (bis(2,4,4-trimethylpentyl)dithiophosphinic acid), a transition in the coordination mode of extracted complexes has been observed between Eu and Gd, but not within the actinide series.

Funder

Basic Energy Sciences

Natural Science Foundation of Beijing Municipality

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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