[E(μ-NBbp)]2 (E = P, As) – group 15 biradicals synthesized from acyclic precursors

Author:

Bresien Jonas1234ORCID,Schulz Axel12345ORCID,Szych Lilian Sophie1234ORCID,Villinger Alexander1234ORCID,Wustrack Ronald1234ORCID

Affiliation:

1. Institut für Chemie

2. Universität Rostock

3. D-18059 Rostock

4. Germany

5. Leibniz-Institut für Katalyse e.V. an der Universität Rostock

Abstract

Starting from an acyclic precursor R–N(ECl2)2, the preparation of biradicals of the type [E(μ-NBbp)]2 (E = P, As) was achieved.

Funder

Deutsche Forschungsgemeinschaft

Studienstiftung des Deutschen Volkes

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference100 articles.

1. A. McNaught and A. D.Wilkinson , IUPAC. Compendium of Chemical Terminology, 2nd Ed. (the “Gold Book”) , Blackwell Scientific Publications , Oxford, UK , 2nd edn, 2006

2. Diradicals

3. Group 15 biradicals: synthesis and reactivity of cyclobutane-1,3-diyl and cyclopentane-1,3-diyl analogues

4. Die elektronischen Eigenschaften von Diradikalen

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