A boron, nitrogen-containing heterocyclic carbene (BNC) as a redox active ligand: synthesis and characterization of a lithium BNC-aurate complex-Reference-Cited by-同舟云学术

A boron, nitrogen-containing heterocyclic carbene (BNC) as a redox active ligand: synthesis and characterization of a lithium BNC-aurate complex

Published:2022 Issue:20 Volume:51 Page:7899-7906
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kimura Yoshitaka¹,Lugo-Fuentes Leonardo I.²,Saito Souta¹,Jimenez-Halla J. Oscar C.²^ORCID,Barroso-Flores Joaquín³^ORCID,Yamamoto Yohsuke¹^ORCID,Nakamoto Masaaki¹,Shang Rong¹^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan

2. Department of Chemistry, Division of Natural and Exact Sciences, University of Guanajuato, Campus Gto, Noria Alta s/n 36050, Guanajuato, Mexico

3. Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM México and Instituto de Química, Universidad Nacional Autónoma de México, Carretera Toluca-Atlacomulco Km. 14.5, Unidad San Cayetano, 50200 Toluca de Lerdo, Ciudad de Méico 04510, Mexico

Abstract

A highly π-withdrawing boryl-substituted N-heterocyclic carbene (ClBNC) was generated at a gold(i) center, which allowed a 2e− reduction to form a 6π BNC-aurate complex, showing the redox active nature of the diboron containing carbene ligand.

Funder

Japan Society for the Promotion of Science

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01083F

Reference59 articles.

1. Adventures with Substances Containing Metals in Negative Oxidation States

2. The chemistry of gold as an anion

3. CCII.—The alkyl compounds of gold

4. Potassium dicyanoaurate(I)–2,2'-bipyridyl

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