The study of the electronic structure of some N-heterocyclic carbenes (NHCs) by variable energy photoelectron spectroscopy-Reference-Cited by-同舟云学术

The study of the electronic structure of some N-heterocyclic carbenes (NHCs) by variable energy photoelectron spectroscopy

Published:2015 Issue:16 Volume:17 Page:10656-10667
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kovač Branka¹²³,Ljubić Ivan¹²³,Kivimäki Antti⁴⁵⁶⁷,Coreno Marcello⁸⁹⁷,Novak Igor¹⁰¹¹¹²

Affiliation:

1. Ruđer Bošković Institute

2. HR-10000 Zagreb

3. Croatia

4. CNR-IOM

5. Laboratorio Nazionale TASC

6. 34149 Trieste

7. Italy

8. CNR-IMIP

9. 00016 Rome

10. Charles Sturt University

11. Orange NSW 2800

12. Australia

Abstract

UV and X-ray photoelectron spectra of three N-heterocyclic carbenes under synchrotron radiation reveal details of their electronic structure and are used as a benchmark to test computational methods for treating core ionizations in systems with unusual electronic structures.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP00482A

Reference62 articles.

1. Stereoelectronic parameters associated with N-heterocyclic carbene (NHC) ligands: A quest for understanding

2. N-Heterocyclic Carbenes: Organocatalysts with Moderate Nucleophilicity but Extraordinarily High Lewis Basicity

3. A Continuum of Progress: Applications of N-Hetereocyclic Carbene Catalysis in Total Synthesis

4. N-Heterocyclic Carbene Catalyzed Domino Reactions

5. Carbenes As Catalysts for Transformations of Organometallic Iron Complexes

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