Manganese catalysed dehydrocoupling of silanes and siloxanes with ammonia to prepare oligosilazanes and polysiloxazanes

Author:

Mehta Gautam K.1ORCID,Nguyen Thao T.1ORCID,Flores Marco1ORCID,Trovitch Ryan J.1ORCID

Affiliation:

1. School of Molecular Sciences, Arizona State University, Tempe, AZ 85287, USA

Abstract

The manganese-catalysed dehydrocoupling of ammonia to phenylsilane affords an oligosilazane that can be applied as a coating.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Reference25 articles.

1. Polymeric methylsilazanes

2. M.Weinmann , in Silicon-based Inorganic Polymers , ed. R. De Jaeger and M. Gleria , Nova Science Publishers , New York , 2008 , ch. 7, pp. 371–414

3. Preparation of moisture curable polysilazane coatings

4. Silicon–Nitrogen Bond Formation via Heterodehydrocoupling and Catalytic N‐Silylation

5. N-Silylamines in catalysis: synthesis and reactivity

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