Reactivities of zero-valent group 10 complexes toward organic isocyanates: synthesis of metallacycles containing dimeric isocyanate units, isocyanate cyclotrimerization, and computational chemistry-Reference-Cited by-同舟云学术

Reactivities of zero-valent group 10 complexes toward organic isocyanates: synthesis of metallacycles containing dimeric isocyanate units, isocyanate cyclotrimerization, and computational chemistry

Published:2019 Issue:39 Volume:43 Page:15614-15625
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Han Young-Sung¹²³⁴⁵^ORCID,Jung Kang-Yeoun⁵²³⁴^ORCID,Kim Yong-Joo¹²³⁴^ORCID,Baeck Kyoung Koo¹²³⁴^ORCID,Lee Gang Min¹⁶⁷⁴,Lee Soon W.¹⁶⁷⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Kangnung-Wonju National University

3. Gangneung 210-702

4. Korea

5. Department of Biochemical Engineering

6. Sungkyunkwan University

7. Suwon 440-746

Abstract

Five-membered metallacycles involving dimeric isocyanate units converted into cyclic tetramers and isocyanurates, depending on the central metal or organic isocyanates, and their synthetic and theoretical studies were carried out.

Funder

Ministry of Education, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ03332G

Reference54 articles.

1. Transition-metal-mediated reactions of organic isocyanates

2. Organic azides and isocyanates as sources of nitrene species in organometallic chemistry

3. Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

4. Lithium, magnesium, zinc complexes supported by tridentate pincer type pyrrolyl ligands: Synthesis, crystal structures and catalytic activities for the cyclotrimerization of isocyanates

5. Bidentate pyrrolyl lithium complexes: Synthesis, crystal structure and catalytic activity for the cyclotrimerization of isocyanates

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