Reactivities of zero-valent group 10 complexes toward organic isocyanates: synthesis of metallacycles containing dimeric isocyanate units, isocyanate cyclotrimerization, and computational chemistry

Author:

Han Young-Sung12345ORCID,Jung Kang-Yeoun5234ORCID,Kim Yong-Joo1234ORCID,Baeck Kyoung Koo1234ORCID,Lee Gang Min1674,Lee Soon W.1674ORCID

Affiliation:

1. Department of Chemistry

2. Kangnung-Wonju National University

3. Gangneung 210-702

4. Korea

5. Department of Biochemical Engineering

6. Sungkyunkwan University

7. Suwon 440-746

Abstract

Five-membered metallacycles involving dimeric isocyanate units converted into cyclic tetramers and isocyanurates, depending on the central metal or organic isocyanates, and their synthetic and theoretical studies were carried out.

Funder

Ministry of Education, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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