Structural and electronic trends for five coordinate 1st row transition metal complexes: Mn(ii) to Zn(ii) captured in a bis(iminopyridine) framework

Author:

Jurca Titel12345,Ouanounou Sarah12345,Shih Wei-Chih6789,Ong Tiow-Gan6789,Yap Glenn P. A.1011121314,Korobkov Ilia12345,Gorelsky Serge12345,Richeson Darrin12345

Affiliation:

1. Department of Chemistry and Biomolecular Sciences

2. Center for Catalysis Research and Innovation

3. University of Ottawa

4. Ottawa

5. Canada

6. Institute of Chemistry

7. Academia Sinica

8. Taipei

9. Taiwan

10. Department of Chemistry & Biochemistry

11. 236 Brown Laboratory

12. University of Delaware

13. Newark

14. USA

Abstract

A series of divalent bis(iminopyridine) complexes {2,6-[PhCN(tBu2C6H3)]2C5H3N}MBr2 provided a unique system for investigating the correlation of experimental structure and electronic structure analysis.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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