Direct synthesis of poly(α-olefin) thermoplastic elastomers <i>via</i> controlled chain straightening using bulky α-diimine palladium complexes-Reference-Cited by-同舟云学术

Direct synthesis of poly(α-olefin) thermoplastic elastomers via controlled chain straightening using bulky α-diimine palladium complexes

Published:2024 Issue:30 Volume:15 Page:3027-3039
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Wang Hui¹,Cai Qi²³,Dai Shengyu²³^ORCID

Affiliation:

1. Department of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, China

2. Institutes of Physical Science and Information Technology, Information Materials and Intelligent Sensing Laboratory of Anhui Province, Anhui University, Hefei, Anhui, 230601, China

3. Anhui Laboratory of Molecule-Based Materials; Key Laboratory of Functional Molecular Solids, Ministry of Education, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241002, China

Abstract

This study uses chain-walking bulky α-diimine Pd(ii) complexes for α-olefin homopolymerization, generating TPEs with high MW, varied branching, and excellent strain/recovery, highlighting catalyst structure's impact.

Funder

Natural Science Foundation of Anhui Province

Hefei Normal University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/PY/D4PY00353E

Reference72 articles.

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