Synthesis of 15N-labeled heterocycles via the cleavage of C–N bonds of anilines and glycine-15N-Reference-Cited by-同舟云学术

Synthesis of 15N-labeled heterocycles via the cleavage of C–N bonds of anilines and glycine-15N

Published:2021 Issue:44 Volume:57 Page:5442-5445
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

He Jiwen¹²³⁴⁵,Zhang Xingguo⁶⁷⁸⁵^ORCID,He Qiuqin⁹²¹⁰¹¹⁵,Guo Hao¹²³⁴⁵^ORCID,Fan Renhua⁹²¹⁰¹¹⁵^ORCID

Affiliation:

1. Academy for Engineering and Technology

2. Fudan University

3. 220 Handan Road

4. Shanghai 200433

5. China

6. College of Chemistry and Materials Engineering

7. Wenzhou University

8. Wenzhou 325035

9. Department of Chemistry

10. 2005 Songhu Road

11. Shanghai 200438

Abstract

A nitrogen replacement process of anilines by glycine-¹⁵N via the cleavage of two C–N bonds for the synthesis of ¹⁵N-labeled aromatic heterocycles was reported.

Funder

Science and Technology Commission of Shanghai Municipality

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01734A

Reference59 articles.

1. Diazonium Salts as Substrates in Palladium-Catalyzed Cross-Coupling Reactions

2. Evolution and Synthetic Applications of the Heck–Matsuda Reaction: The Return of Arenediazonium Salts to Prominence

3. Recent advances in the Heck–Matsuda reaction in heterocyclic chemistry

4. Recent applications of arene diazonium salts in organic synthesis

5. Enantioselective 1,1-Arylborylation of Alkenes: Merging Chiral Anion Phase Transfer with Pd Catalysis

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