Benzyne addition to a metal–carbon multiple bond
Author:
Affiliation:
1. Research School of Chemistry
2. Australian National University
3. Canberra
4. Australia
Abstract
Benzyne (dehydrobenzene) is shown to add across the RhC multiple bond of a dirhodium carbido complex to afford a cyclometallated μ-benzylidyne complex.
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01402A
Reference75 articles.
1. Alkyne metathesis by molybdenum and tungsten alkylidyne complexes
2. Lessons from Natural Product Total Synthesis: Macrocyclization and Postcyclization Strategies
3. Synthesis of monomeric niobium- and tantalum-benzyne complexes and the molecular structure of Ta(.eta.5-C5Me5)(C6H4)Me2
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