Recyclable and efficient polyurethane-Ir catalysts for direct borylation of aromatic compounds

Author:

Kimura Akihiro1234,Hayama Haruka1234,Hasegawa Jun-ya12345ORCID,Nageh Hassan1234,Wang Yue1234,Naga Naofumi6784ORCID,Nishida Mayumi12345ORCID,Nakano Tamaki12345ORCID

Affiliation:

1. Institute for Catalysis (ICAT) and Graduate School of Chemical Sciences and Engineering

2. Hokkaido University

3. Sapporo 001-0021

4. Japan

5. Integrated Research Consortium on Chemical Sciences (IRCCS)

6. Graduate School of Science and Engineering

7. Shibaura Institute of Technology

8. Koto-ku Tokyo 135-8548

Abstract

Four polyurethanes comprising 2,2′-bipyridyl moieties incorporated in the main chain were synthesized as novel polymer ligands for the Ir(i)-catalyzed direct borylation of aromatic compounds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference66 articles.

1. T. E. Kristensen and T.Hansen , Polymer and Mesoporous Material Supported Organocatalysts , in Comprehensive Enantioselective Organocatalysis: Catalysts, Reactions, and Applications , ed. P. I. Dalko , Wiley-VCH , Weinheim , 2013 , pp. 651–672

2. Polymer-Supported Organic Catalysts

3. Using Soluble Polymers To Recover Catalysts and Ligands

4. Organic Polymer Supports for Synthesis and for Reagent and Catalyst Immobilization

5. Recoverable Catalysts for Asymmetric Organic Synthesis

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