Amine additive reactions induced by the soft Lewis acidity of Pb2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation-Reference-Cited by-同舟云学术

Amine additive reactions induced by the soft Lewis acidity of Pb2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation

Published:2019 Issue:18 Volume:7 Page:5251-5259
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Kerner Ross A.¹²³⁴^ORCID,Schloemer Tracy H.⁵⁶⁷⁸⁴^ORCID,Schulz Philip⁹⁷⁸⁴¹⁰,Berry Joseph J.⁹⁷⁸⁴^ORCID,Schwartz Jeffrey⁵²³⁴,Sellinger Alan⁵⁶⁷⁸⁴^ORCID,Rand Barry P.¹²³⁴¹¹^ORCID

Affiliation:

1. Department of Electrical Engineering

2. Princeton University

3. Princeton

4. USA

5. Department of Chemistry

6. Colorado School of Mines

7. Golden

8. Colorado 80401

9. National Renewable Energy Laboratory

10. CNRS, Institut Photovoltaïque d'Ile de France (IPVF)

11. Andlinger Center for Energy and the Environment

Abstract

Simple aliphatic amine additives are shown to react with PbI₂ in perovskite inks to form amido Pb and alkylammonium species.

Funder

Solar Energy Technologies Program

Office of Naval Research Global

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/TC/C8TC04871A

Reference38 articles.

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5. Degradation of Highly Alloyed Metal Halide Perovskite Precursor Inks: Mechanism and Storage Solutions

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