Reactivity of the diphosphinodithio ligated nickel(0) complex toward alkyl halides and resultant nickel(i) and nickel(ii)

Reactivity of the diphosphinodithio ligated nickel(0) complex toward alkyl halides and resultant nickel(i) and nickel(ii)–alkyl complexes

Published:2018 Issue:44 Volume:47 Page:15757-15764
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Ailing¹²³⁴⁵,Wang Congxiao¹²³⁴⁵,Lai Xiaoyu¹²³⁴⁵,Zhai Xiaofang¹²³⁴⁵,Pang Maofu¹²³⁴⁵,Tung Chen-Ho¹²³⁴⁵,Wang Wenguang¹²³⁴⁵^ORCID

Affiliation:

1. Key Lab for Colloid and Interface Chemistry of Education Ministry

2. School of Chemistry and Chemical Engineering

3. Shandong University

4. Jinan 250100

5. PR China

Abstract

Diphosphinodithio ligated complexes of nickel(0), nickel(i) and nickel(ii)–alkyl with a reactivity relevant to the C–C bond formation were described.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03188F

Reference65 articles.

1. A. M. Echavarren and D. J.Cardenas , in Metal-Catalyzed Cross-Coupling Reactions , ed. A. de Meijere and F. Diederich , Wiley, VCH , 2nd edn, 2004 , ch. 1, pp. 1–40

2. Recent advances in homogeneous nickel catalysis

3. Nickel and Iron Pincer Complexes as Catalysts for the Reduction of Carbonyl Compounds

4. Complexes of Ni(i): a “rare” oxidation state of growing importance

5. Suzuki Cross-Couplings of Unactivated Secondary Alkyl Bromides and Iodides

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Tetradentate square-planar acetylumbelliferone–nickel (II) complex formation: a DFT and TD-DFT study;Theoretical Chemistry Accounts;2022-08-25

2. The Effect of Added Ligands on the Reactions of [Ni(COD)(dppf)] with Alkyl Halides: Halide Abstraction May Be Reversible;Organometallics;2021-06-16

3. Reactions of nickel(0) with organochlorides, organobromides, and organoiodides: mechanisms and structure/reactivity relationships;Catalysis Science & Technology;2021

4. Unexpected Nickel Complex Speciation Unlocks Alternative Pathways for the Reactions of Alkyl Halides with dppf-Nickel(0);ACS Catalysis;2020-08-21

5. Silver(I)‐Based Complexes Used as High‐Performance Photocatalysts for the Degradation of Organic Dyes in Water;European Journal of Inorganic Chemistry;2019-02-28