High-valence CuIICuIII species in action: demonstration of aliphatic C–H bond activation at room temperature-Reference-Cited by-同舟云学术

High-valence CuIICuIII species in action: demonstration of aliphatic C–H bond activation at room temperature

Published:2019 Issue:84 Volume:55 Page:12711-12714
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Isaac James A.¹²³⁴⁵,Thibon-Pourret Aurore¹²³⁴⁵^ORCID,Durand Amélie¹²⁶⁴⁵,Philouze Christian¹²³⁴⁵,Le Poul Nicolas⁷⁸⁹⁵^ORCID,Belle Catherine¹²³⁴⁵^ORCID

Affiliation:

1. Université Grenoble Alpes

2. CNRS

3. DCM

4. 38000 Grenoble

5. France

6. ICMG

7. Université de Bretagne Occidentale

8. CNRS UMR 6521

9. 29238 Brest

Abstract

The electrochemically generated Cu^IICu^III mixed-valence species promotes activation of strong aliphatic C–H bonds (i.e. toluene), turning from stoichiometric to catalytic upon addition of a base.

Funder

Agence Nationale de la Recherche

LABoratoires d’EXcellence ARCANE

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC04422A

Reference44 articles.

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5. Copper–Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity

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