Asymmetric hydrogenation of an α-unsaturated carboxylic acid catalyzed by intact chiral transition metal carbonyl clusters – diastereomeric control of enantioselectivity-Reference-Cited by-同舟云学术

Asymmetric hydrogenation of an α-unsaturated carboxylic acid catalyzed by intact chiral transition metal carbonyl clusters – diastereomeric control of enantioselectivity

Published:2020 Issue:14 Volume:49 Page:4244-4256
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Abdel-Magied Ahmed F.¹²³⁴⁵^ORCID,Theibich Yusuf¹²³⁴⁵,Singh Amrendra K.¹²³⁴⁵^ORCID,Rahaman Ahibur¹²³⁴⁵,Doverbratt Isa⁶²³⁴⁵,Raha Arun K.¹²³⁴⁵,Haukka Matti²⁷⁸⁹^ORCID,Richmond Michael G.²¹⁰¹¹¹²^ORCID,Nordlander Ebbe¹²³⁴⁵^ORCID

Affiliation:

1. Chemical Physics

2. Department of Chemistry

3. Lund University

4. Lund

5. Sweden

6. Centre for Analysis and Synthesis

7. University of Jyväskylä

8. Jyväskylä

9. Finland

10. The University of North Texas

11. Denton

12. USA

Abstract

Asymmetric hydrogenation catalysis by [(μ-H)₂Ru₃(μ₃-S)(CO)₇(μ-P–P*)] (P–P* = chiral diphosphine) indicates intact chiral clusters as active catalysts.

Funder

Carl Tryggers Stiftelse för Vetenskaplig Forskning

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04799A

Reference48 articles.

1. Dehydrogenation of organic and inorganic molecules by reaction with Os3 (CO)12

2. Sulfur Atoms as Ligands in Metal Complexes