Bending and precipitate formation mechanisms in epitaxial Ge-core/GeSn-shell nanowires

Author:

Meng Andrew C.1ORCID,Wang Yanming23ORCID,Braun Michael R.1,Lentz J. Zach1,Peng Siying1,Cheng Huikai4,Marshall Ann F.5,Cai Wei6,McIntyre Paul C.1

Affiliation:

1. Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305, USA

2. Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA

3. University of Michigan-Shanghai Jiao Tong University Joint Institute, Shanghai Jiao Tong University, Shanghai, China 200240

4. ThermoFisher Scientific, Hillsboro, OR 97124, USA

5. Stanford Nano Shared Facility, Stanford University, Stanford, CA 94305, USA

6. Department of Mechanical Engineering, Stanford University, Stanford, CA 94305, USA

Abstract

The balance between Sn precursor flux and available surfaces for GeSn nucleation and growth determines whether the nanowire bends or precipitates form. When growth is precursor flux limited, bending occurs; when growth is adatom attachment site limited, Sn precipitates form.

Funder

National Science Foundation

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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