Copper-catalysed borylation of aryl chlorides-Reference-Cited by-同舟云学术

Copper-catalysed borylation of aryl chlorides

Published:2019 Issue:27 Volume:17 Page:6601-6606
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Kuehn Laura¹²³⁴,Huang Mingming¹²³⁴,Radius Udo¹²³⁴^ORCID,Marder Todd B.¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische Chemie and Institute for Sustainable Chemistry & Catalysis with Boron

2. Julius-Maximilians-Universität Würzburg

3. 97074 Würzburg

4. Germany

Abstract

The first example of a Cu-catalysed borylation of a wide range of aryl chlorides with different electronic and steric properties is mediated by a readily prepared NHC-stabilised Cu catalyst and KO^tBu. The aryl chlorides are converted into their corresponding arylboronic esters using B₂pin₂ or B₂neop₂ as the boron reagent.

Funder

Julius-Maximilians-Universität Würzburg

Deutsche Forschungsgemeinschaft

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB01244C

Reference87 articles.

1. Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse