Well-defined triblock copolymers of polyethylene with polycaprolactone or polystyrene using a novel difunctional polyhomologation initiator
Author:
Affiliation:
1. King Abdullah University of Science and Technology (KAUST)
2. Physical Sciences and Engineering Division
3. KAUST Catalysis Center
4. Polymer Synthesis Laboratory
5. Thuwal 23955
Abstract
α,ω-Dihydroxy polyethylene, valuable precursor for the synthesis of polyethylene-based terpolymers with polar blocks, was synthesized by polyhomologation of dimethylsulfoxonium methylide with 9-thexyl-9-BBN, a novel difunctional initiator with two active and one blocked sites.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2017/PY/C7PY01079F
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