Investigation of the full reversal of selectivity in the reaction of aniline with 1,3-dichloro-1,3-bis(dimethylamino)vinamidinium salts
Author:
Affiliation:
1. Université Grenoble-Alpes, CNRS, DCM (UMR 5250), CS 40700
2. 38058 Grenoble Cedex 9
3. France
Abstract
Changing the timing of the addition of triethylamine switches this reaction towards the formation of either a quinoline or a malonamidine.
Funder
Agence Nationale de la Recherche
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ03442C
Reference50 articles.
1. Reaction of Dichloromethylenedimethylammonium Chloride (?Phosgene Immonium Chloride?) with Carbonyl-Activated Methylene Groups
2. Condensation of Dichloromethylenedimethyl-ammonium Chloride (?Phosgene Immonium Chloride?) withN,N-Dialkylcarboxamides
3. Neues aus der Chemie der Iminiumsalze
4. Allentetramine und Dialkoxy-diamino-allene
5. Phosgene immonium salts. XIII. Dichloromalonyl cyanines and 3,5-bis(dimethylamino)pyrazoles
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