Silylation reactions on nanoporous gold via homolytic Si–H activation of silanes-Reference-Cited by-同舟云学术

Silylation reactions on nanoporous gold via homolytic Si–H activation of silanes

Published:2018 Issue:21 Volume:9 Page:4808-4813
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Hongbo¹²³⁴⁵,Guo Huifang¹²³⁴⁵,Li Zhiwen⁶⁷⁸⁵,Wu Cai¹²³⁴⁵,Li Jing¹²³⁴⁵,Zhao Chunliang¹²³⁴⁵,Guo Shuangxi¹²³⁴⁵,Ding Yi⁶⁷⁸⁵,He Wei¹²³⁴⁵^ORCID,Li Yadong⁹³⁴⁵^ORCID

Affiliation:

1. Tsinghua-Peking Joint Centers for Life Sciences

2. School of Pharmaceutical Sciences

3. Tsinghua University

4. Beijing 100084

5. China

6. Tianjin Key Laboratory of Advanced Functional Porous Materials

7. Tianjin University of Technology

8. Tianjin 300384

9. Department of Chemistry

Abstract

We report compelling evidences that dihydrosilanes are activated in a homolytic fashion on the surface of nanoporous gold (NPG), which produces hydrogen radical and silicon moieties covalently linked to the surface of the NPG. This new reactivity has led to the development of novel silylation reactions on gold.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01427B

Reference64 articles.

1. B. Marciniec , Hydrosilylation: a comprehensive review on recent advances , Springer Science & Business Media , 2008

2. Catalytic Silylation of Unactivated C–H Bonds

3. Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel-Crafts C−H Silylation

4. Nanoporous Gold Catalyst for Highly Selective Semihydrogenation of Alkynes: Remarkable Effect of Amine Additives

Cited by 22 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Organophosphonic acid catalyzed dehydrogenative coupling of hydrosilanes with alcohols under solvent-free conditions;Main Group Metal Chemistry;2024-01-01

2. Organic Synthesis Catalyzed by Nanoporous Metals;Molecular Catalysis;2024

3. Nanoporous Gold: From Structure Evolution to Functional Properties in Catalysis and Electrochemistry;Chemical Reviews;2023-05-03

4. Deoxygenative Silylation of C(sp³)–O Bonds with Hydrosilane by Cooperative Catalysis of Gold Nanoparticles and Solid Acids;ACS Catalysis;2023-05-03

5. Diverse Alkyl–Silyl Cross-Coupling via Homolysis of Unactivated C(sp³)–O Bonds with the Cooperation of Gold Nanoparticles and Amphoteric Zirconium Oxides;Journal of the American Chemical Society;2023-02-20