Photochemical rearrangement reactions of bicyclic molecules that contain a cyclopropane ring

Author:

Su Shih-Hao1234,Su Ming-Der12345ORCID

Affiliation:

1. Department of Applied Chemistry

2. National Chiayi University

3. Chiayi 60004

4. Taiwan

5. Department of Medicinal and Applied Chemistry

Abstract

Our theoretical observations indicate that for [2.1.0], [3.1.0], [4.1.0], and [5.1.0] molecules, the quantum yields of the tautomeric keto forms are larger than those of the corresponding enol isomers.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference65 articles.

1. J. Birks , Photophysics of Aromatic Molecules , Wiley , New York , 1970

2. F. Wilkinson , in Organic Molecular Photophysics , ed. J. Birks , Wiley , New York , 1975 , p. 95

3. K. Schaffner and M.Demuth , Photochemical Rearrangements of Conjugated Cyclic Dienones , in Rearrangements in Ground and Excited States , ed. P. de Mayo , Academic Press , New York , 1980 , vol. 3, p. 481

4. A. G. Schultz , Rearrangement Reactions of Cross-Conjugated Cyclohexadienones , in CRC Handbook of Photochemistry and Photobiology , ed. W. M. Horspool , CRC Press , Boca Raton , 1995 , p. 685

5. A. G. Schultz , Cyclohexadienone Photochemistry: Trapping Reactions , in CRC Handbook of Photochemistry and Photobiology , W. M. Horspool , CRC Press , Boca Raton , 1995 , p. 716

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