Nickel(ii) complexes based on dithiolate–polyamine binary ligand systems: crystal structures, hirshfeld surface analysis, theoretical study, and catalytic activity study on photocatalytic hydrogen generation

Author:

Adhikari Suman1234ORCID,Bhattacharjee Tirtha1564,Bhattacharjee Sharmila1234ORCID,Daniliuc Constantin Gabriel78910ORCID,Frontera Antonio11121314ORCID,Lopato Eric M.1151617,Bernhard Stefan1151617ORCID

Affiliation:

1. Department of Chemistry

2. Govt. Degree College

3. Dharmanagar

4. India

5. Bineswar Brahma Engineering College

6. Kokrajhar-783370

7. Organisch-Chemisches Institut

8. Westfälische Wilhelms-Universität Münster

9. Münster

10. Germany

11. Department de Quimica

12. Universitat de les Illes Balears

13. 07122 Palma de Mallorca

14. Spain

15. Carnegie Mellon University

16. Pittsburgh

17. USA

Abstract

To ascertain the influence of binary ligand systems on the coordination modes of the Ni(ii) metal center and resulting supramolecular architectures, three Ni(ii) thiolate complexes have been synthesized in high yield in one step in water and structurally characterized.

Funder

National Science Foundation

Carnegie Mellon University

Achievement Rewards for College Scientists Foundation

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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