Direct and remote control of electronic structures and redox potentials in μ-oxo diferric complexes-Reference-Cited by-同舟云学术

Direct and remote control of electronic structures and redox potentials in μ-oxo diferric complexes

Published:2023 Issue:46 Volume:52 Page:17548-17561
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Finke Sebastian¹,Stammler Anja¹,Oldengott Jan¹,Walleck Stephan¹,Glaser Thorsten¹^ORCID

Affiliation:

1. Lehrstuhl für Anorganische Chemie I, Fakultät für Chemie, Universität Bielefeld, Universitätsstr. 25, D-33615 Bielefeld, Germany

Abstract

The potential for the oxidation shifted cathodically by 590 mV by substituting the exogenous ligand from OAc− to OH−. The potential of the complex with mixed OH−/OAc− is the mean value of the potentials of OH−/OH− and OAc−/OAc− complexes.

Funder

Deutsche Forschungsgemeinschaft

Universität Bielefeld

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02734A

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5. Substrate-Triggered μ-Peroxodiiron(III) Intermediate in the 4-Chloro-l-Lysine-Fragmenting Heme-Oxygenase-like Diiron Oxidase (HDO) BesC: Substrate Dissociation from, and C4 Targeting by, the Intermediate

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