Interrogating the thionium hydrogen bond as a noncovalent stereocontrolling interaction in chiral phosphate catalysis-Reference-Cited by-同舟云学术

Interrogating the thionium hydrogen bond as a noncovalent stereocontrolling interaction in chiral phosphate catalysis

Published:2022 Issue:37 Volume:13 Page:11065-11073
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lai Junshan¹,Reid Jolene P.¹^ORCID

Affiliation:

1. Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, V6T 1Z1, Canada

Abstract

Transferable selectivity profiles allow data from intermolecular reactions using iminium substrates to be applied to predict intramolecular reactions involving thioniums.

Funder

University of British Columbia

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02171D

Reference61 articles.

1. Comparing quantitative prediction methods for the discovery of small-molecule chiral catalysts

2. Open questions on the transfer of chirality

3. Transition State Models for Understanding the Origin of Chiral Induction in Asymmetric Catalysis

4. Noncovalent Interactions in Organocatalysis and the Prospect of Computational Catalyst Design

5. Computational prediction of small-molecule catalysts

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