Validity of the Onsager–Glarum relationship in a molecular coulomb fluid: investigation via temperature-dependent molecular dynamics simulations of a representative ionic liquid, [BMIM][PF6]

Abstract

Temperature dependent (T = 298–450 K) molecular dynamics simulations were carried out with the ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]), in order to explore the validity of the Onsager–Glarum (OG) relationship.