Why do zeolites induce an unprecedented electronic state on exchanged metal ions?-Reference-Cited by-同舟云学术

Why do zeolites induce an unprecedented electronic state on exchanged metal ions?

Published:2017 Issue:36 Volume:19 Page:25105-25114
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Oda Akira¹²³⁴⁵,Ohkubo Takahiro⁵⁶⁷⁸⁴^ORCID,Yumura Takashi⁹¹⁰¹¹⁴^ORCID,Kobayashi Hisayoshi⁹¹⁰¹¹⁴,Kuroda Yasushige⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. Precursory Research for Embryonic Science and Technology

2. Japan Science and Technology Agency

3. Kawaguchi

4. Japan

5. Department of Chemistry

6. Graduate School of Natural Science and Technology

7. Okayama University

8. Okayama 700-8530

9. Department of Chemistry and Materials Technology

10. Kyoto Institute of Technology

11. Kyoto 606-8585

Abstract

Understanding the exact position and the detailed role of the Al array in zeolites is essential for elucidating the origin of unique properties and for designing zeolite materials with high efficiency in catalytic and adsorption processes. In this work, we advanced pivotal roles of Lewis base–metal ion bifunctionality caused by Al atoms arrayed circumferentially in the MFI-zeolite pores.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP02669B

Reference84 articles.

1. Specificity of Sites within Eight-Membered Ring Zeolite Channels for Carbonylation of Methyls to Acetyls

2. Enzyme-like Specificity in Zeolites: A Unique Site Position in Mordenite for Selective Carbonylation of Methanol and Dimethyl Ether with CO

3. Correlation between Brønsted Acid Strength and Local Structure in Zeolites

4. Catalytic Consequences of Spatial Constraints and Acid Site Location for Monomolecular Alkane Activation on Zeolites

5. Effects of Partial Confinement on the Specificity of Monomolecular Alkane Reactions for Acid Sites in Side Pockets of Mordenite

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