The electronic structure and deexcitation pathways of an isolated metalloporphyrin ion resolved by metal L-edge spectroscopy-Reference-Cited by-同舟云学术

The electronic structure and deexcitation pathways of an isolated metalloporphyrin ion resolved by metal L-edge spectroscopy

Published:2021 Issue:11 Volume:12 Page:3966-3976
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Schubert Kaja¹²³^ORCID,Guo Meiyuan⁴⁵⁶⁷⁸^ORCID,Atak Kaan¹²³,Dörner Simon¹²³^ORCID,Bülow Christine⁹¹⁰¹¹³,von Issendorff Bernd¹²¹³¹⁴³,Klumpp Stephan¹²³^ORCID,Lau J. Tobias⁹¹⁰¹¹³¹²^ORCID,Miedema Piter S.¹²³^ORCID,Schlathölter Thomas¹⁵¹⁶¹⁷¹⁸^ORCID,Techert Simone¹²³¹⁹²⁰^ORCID,Timm Martin⁹¹⁰¹¹³^ORCID,Wang Xin¹⁵¹⁶¹⁷¹⁸,Zamudio-Bayer Vicente⁹¹⁰¹¹³^ORCID,Schwob Lucas¹²³^ORCID,Bari Sadia¹²³^ORCID

Affiliation:

1. Deutsches Elektronen-Synchrotron DESY

2. 22607 Hamburg

3. Germany

4. Division of Chemical Physics

5. Chemical Center

6. Lund University

7. SE-221 00 Lund

8. Sweden

9. Abteilung für Hochempfindliche Röntgenspektroskopie

10. Helmholtz-Zentrum Berlin für Materialien und Energie

11. 12489 Berlin

12. Physikalisches Institut

13. Albert-Ludwigs-Universität Freiburg

14. 79104 Freiburg

15. Zernike Institute for Advanced Materials

16. University of Groningen

17. 9747 AG Groningen

18. The Netherlands

19. Institut für Röntgenphysik

20. Georg-August-Universität Göttingen

Abstract

Near-edge X-ray absorption mass spectrometry (NEXAMS) and restricted active space (RAS) quantum mechanical calculations at the metal L-edge reveal the electronic structure and orbital-specific deexcitation pathways of gas-phase metalloporphyrins.

Funder

Bundesministerium für Bildung und Forschung

Deutsche Forschungsgemeinschaft

Helmholtz Association

Knut och Alice Wallenbergs Stiftelse

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06591A

Reference72 articles.

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3. Induction of the Heme Oxygenase-1 Gene by Metalloporphyrins

4. Photodynamic Therapy and the Development of Metal-Based Photosensitisers

5. The role of porphyrin chemistry in tumor imaging and photodynamic therapy

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