Synthesis and optical properties of antimony(<scp>v</scp>) complexes of a trianionic N<sub>2</sub>O<sub>2</sub>-type tetradentate dipyrrin ligand-Reference-Cited by-同舟云学术

Synthesis and optical properties of antimony(v) complexes of a trianionic N₂O₂-type tetradentate dipyrrin ligand

Published:2024 Issue:34 Volume:60 Page:4557-4560
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Agou Tomohiro¹^ORCID,Kuroiwa Shunsuke²,Fukumoto Hiroki²^ORCID,Nabeshima Tatsuya³^ORCID

Affiliation:

1. Department of Material Science, Graduate School of Science, University of Hyogo, 3-2-1 Kouto, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan

2. Department of Quantum Beam Science, Graduate School of Science and Engineering, Ibaraki University, 4-12-1 Naka-narusawa, Hitachi, Ibaraki 316-8511, Japan

3. Institute of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan

Abstract

An Sb(v) complex of a trianionic N2O2-type tetradentate dipyrrin ligand was obtained by a photochemical reaction between SbCl3 and the ligand in an O2 atmosphere. Replacing the axial Cl ligands with OH ligands resulted in substantial fluorescence enhancement.

Funder

Murata Science Foundation

Hitachi Global Foundation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00630E

Reference47 articles.

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5. Dipyrrin based metal complexes: reactivity and catalysis