A dipyrromethane-based diphosphane–germylene as precursor to tetrahedral copper(i) and T-shaped silver(i) and gold(i) PGeP pincer complexes

Author:

Cabeza Javier A.1234ORCID,Fernández Israel56784ORCID,García-Álvarez Pablo1234ORCID,Laglera-Gándara Carlos J.1234ORCID

Affiliation:

1. Centro de Innovación en Química Avanzada (ORFEO-CINQA) and Departamento de Química Orgánica e Inorgánica

2. Universidad de Oviedo

3. 33071 Oviedo

4. Spain

5. Centro de Innovación en Química Avanzada (ORFEO-CINQA) and Departamento de Química Orgánica I

6. Facultad de Ciencias Químicas

7. Universidad Complutense de Madrid

8. 28040 Madrid

Abstract

A dipyrromethane-based PGeP germylene has allowed the synthesis of unusual tetrahedral copper(i) and T-shaped silver(i) and gold(i) germyl complexes.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference84 articles.

1. Key factors in pincer ligand design

2. The Privileged Pincer–Metal Platform: Coordination Chemistry & Applications , ed. G. van Koten and R. A. Gossage , Springer , Cham , 2016

3. Non-symmetric pincer ligands: complexes and applications in catalysis

4. Bond Activation and Catalysis by Ruthenium Pincer Complexes

5. The Chemistry of Pincer Compounds , ed. K. J. Szabó and O. F. Wendt , Wiley-VCH , Weinheim , 2014

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