Chloranilate bridged dinuclear copper(ii) complexes: syn–anti geometry tuned by the steric factor and supramolecular interactions
Author:
Affiliation:
1. Department of Chemistry
2. University College of Science
3. University of Calcutta
4. Kolkata-700 009
5. India
6. Departament de Química
7. Universitat de les IllesBalears
8. 07122 Palma de Mallorca
9. Spain
Abstract
The anti-conformation of chloranilate bridged di-copper complexes of NNO donor Schiff-base ligands is more stable than the syn-conformation, but the latter is stabilised by CH⋯π and hydrogen bonding interactions between solvent of crystallisation and chloranilate moieties.
Funder
Ministerio de Economía y Competitividad
Department of Science and Technology, Ministry of Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CE/C9CE00705A
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