High-spin, tetrahedral cobalt(<scp>ii</scp>) and nickel(<scp>ii</scp>) complexes supported by monoprotic aminophosphine ligands, and attempted extension to copper(<scp>ii</scp>) complexes: synthesis, characterization, and unexpected reactivity-Reference-Cited by-同舟云学术

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High-spin, tetrahedral cobalt(ii) and nickel(ii) complexes supported by monoprotic aminophosphine ligands, and attempted extension to copper(ii) complexes: synthesis, characterization, and unexpected reactivity

Published:2022 Issue:39 Volume:46 Page:18647-18651
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kelly Jordan C.¹,Bloomfield Aaron J.¹^ORCID

Affiliation:

1. Department of Chemistry & Biochemistry, Duquesne University, 600 Forbes Ave. Pittsburgh, PA 15282, USA

Abstract

We report the synthesis and characterization of two bidentate ligands containing an aliphatic monoprotic aminophosphine moiety, as well as novel complexes with Co(ii), Ni(ii), and Cu(ii).

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ02651A

Reference26 articles.

1. Reaction of [(tmeda)NiMe2] with 2-pyridylmethylamine and (2-pyridylmethyl)(diphenylphosphanyl)amine

2. Dehydrogenative Coupling of Ethanol and Ester Hydrogenation Catalyzed by Pincer-Type YNP Complexes

3. Six-coordinate high-spin iron(ii) complexes with bidentate PN ligands based on 2-aminopyridine – new Fe(ii) spin crossover systems

4. Tuning the photophysical properties of a (P,N)ReI complex by adding a –NH– fragment into a P,N-bidentate ligand: The case of [P,N-{(C6H5)2(C5H4N)NHPRe(CO)3Br]

5. Ethylene (co)Oligomerization by Phosphine‐Pyridine Based Palladium and Nickel Catalysts

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