Photocatalytic hydrogen production by donor–π–acceptor type covalent triazine frameworks involving different π bridges

Author:

Li Xiangyu12,Chen Minghui12,Shi Quan12,Xiong Ji12,Li Ting12,Jiang Yu12,Feng Yaqing12,Zhang Bao123ORCID

Affiliation:

1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China

2. Guangdong Laboratory of Chemistry and Fine Chemical Industry Jieyang Center, Guangdong Province, 522000, P. R. China

3. Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China

Abstract

A novel pyridine-bridged covalent triazine framework (CTF), BenP-CTF, exhibited much higher photocatalytic activity for water splitting to hydrogen than benzene-bridged Ben-CTF and thiophene-bridged BenT-CTF due to enhanced built-in electric field.

Funder

Basic and Applied Basic Research Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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