Expedient assembly of densely functionalized indanonesvianickel-catalyzed alkene hydroacylation with methyl esters

Author:

Zeng Min1,Huang Fuli1,Zhu Minghui1,Ding Jichao1,Qin Tong1,Xu Maoting1,Liu Wanqing1,Lu Jun1ORCID,Wu Jicheng2,Qin Xurong1,Ren Qiao1ORCID

Affiliation:

1. Key Laboratory of Luminescence Analysis and Molecular Sensing (Southwest University), Ministry of Education, College of Pharmaceutical Science, Southwest University, Chongqing 400715, P. R. China

2. Chongqing Key Laboratory of Natural Product Synthesis and Drug Research, Innovative Drug Research Center, School of Pharmaceutical Sciences, Chongqing University, Chongqing 401331, P. R. China

Abstract

A concise nickel-catalyzed intramolecular alkene hydroacylation with readily available but inert methyl esters as acyl electrophiles is disclosed, affording various antioxidant indanones and indazolones in good efficiency.

Funder

Fundamental Research Funds for the Central Universities

Venture and Innovation Support Program for Chongqing Overseas Returnees

National Natural Science Foundation of China

Chongqing Research Program of Basic Research and Frontier Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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