Synthesis and electronic investigation of mono- and di-substituted 4-nitro- and 4-amino-pyrazol-1-yl bis(pyrazol-1-yl)pyridine-type ligands and luminescent Eu(iii) derivatives
Author:
Affiliation:
1. Department of Chemistry
2. The University of Texas at Austin
3. Austin
4. USA
5. Current address: No current affiliation
Abstract
The synthesis of nitro- and amino-bis(pyrazol-1-yl)pyridines was achieved, allowing for tuning of frontier orbital energies and Eu(iii) complex spectroscopic investigations.
Funder
Welch Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01153A
Reference48 articles.
1. Iron(II) complexes of 2,6-di(pyrazol-1-yl)pyridines—A versatile system for spin-crossover research
2. Lanthanide-Containing Light-Emitting Organic-Inorganic Hybrids: A Bet on the Future
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4. Bioconjugated lanthanide luminescent helicates as multilabels for lab-on-a-chip detection of cancer biomarkers
5. Redox regulation in ruthenium(II) complexes of 2,6-bis(N-pyrazolyl)pyridine ligands: synthetically versatile analogs of 2,2':6',2''-terpyridine
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