An extended π-system and enhanced electronic delocalization on symmetric [Ru3O(CH3COO)6(L)3]n complexes combined with azanaphthalene ligands-Reference-Cited by-同舟云学术

An extended π-system and enhanced electronic delocalization on symmetric [Ru3O(CH3COO)6(L)3]n complexes combined with azanaphthalene ligands

Published:2017 Issue:24 Volume:46 Page:7926-7938
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Possato Bruna¹²³⁴,Deflon Victor M.⁵⁶⁴,Naal Zeki⁷³⁴,Formiga André L. B.⁸⁹⁴^ORCID,Nikolaou Sofia¹²³⁴^ORCID

Affiliation:

1. Departamento de Química – Faculdade de Filosofia

2. Ciências e Letras de Ribeirão Preto - Universidade de São Paulo – Av. Bandeirantes

3. Ribeirão Preto

4. Brazil

5. Departamento de Química e Física Molecular - Instituto de Química de São Carlos - Universidade de São Paulo - Av. Trabalhador São Carlense

6. São Carlos

7. Faculdade de Ciências Farmacêuticas de Ribeirão Preto - Universidade de São Paulo – Av. do Café s/no.

8. Instituto de Química – Universidade Estadual de Campinas

9. Campinas

Abstract

The electronic density of the metallic core relies on the basicity of the ligands through σ-donation, while part of this electronic density is delocalized to the periphery through π-interactions.

Funder

São Paulo Research Foundation

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01152K

Reference48 articles.

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