The effect of rigidity on the emission of quadrupolar strongly polarized dyes

Author:

Szymański Bartosz12,Sahoo Smruti Ranjan3,Valiev Rashid4,Vakuliuk Olena1,Łaski Piotr2,Jarzembska Katarzyna N.2,Kamiński Radosław2ORCID,Baryshnikov Glib35ORCID,Teimouri Mohammad B.16ORCID,Gryko Daniel T.1ORCID

Affiliation:

1. Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland

2. Department of Chemistry, University of Warsaw, Żwirki i Wigury 101, 02-089 Warsaw, Poland

3. Laboratory of Organic Electronics, Department of Science and Technology, Linköping University, SE-60174, Norrköping, Sweden

4. Department of Chemistry, University of Helsinki, FI-00014, Helsinki, Finland

5. Department of Chemistry and Nanomaterials Science, Bohdan Khmelnytsky National University, 18031 Cherkasy, Ukraine

6. Faculty of Chemistry, Kharazmi University, 15719-14911 Tehran, Iran

Abstract

Planarization of the pyrrolopyrrole chromophore switches the mechanism of non-radiative deactivation from intersystem crossing to internal conversion.

Funder

Svenska Forskningsrådet Formas

Narodowe Centrum Nauki

Olle Engkvists Stiftelse

Norges Forskningsråd

Academy of Finland

Ministry of Education and Science of Ukraine

Publisher

Royal Society of Chemistry (RSC)

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