Assembling triazolated calix[4]semitubes by means of copper(i)-catalyzed azide–alkyne cycloaddition

Author:

Gorbunov Alexander1234ORCID,Ozerov Nikolay1234,Malakhova Maria1234,Eshtukov Artur564ORCID,Cheshkov Dmitry564ORCID,Bezzubov Stanislav7834ORCID,Kovalev Vladimir1234ORCID,Vatsouro Ivan1234ORCID

Affiliation:

1. Department of Chemistry

2. M. V. Lomonosov Moscow State University

3. 119991 Moscow

4. Russia

5. State Research Institute for Chemistry and Technology of Organoelement Compounds

6. 105118 Moscow

7. Kurnakov Institute of General and Inorganic Chemistry

8. Russian Academy of Sciences

Abstract

Calix[4]arene-based bis(alkynes) and bis(azides) react with each other under thoroughly tuned CuAAC conditions and produce diverse biscalixarene semitube assemblies linked by two triazole units, which are capable of binding transition metal cations.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference73 articles.

1. Calixarenes 2001 , ed. Z. Asfari , V. Böhmer , J. Harrowfield and J. Vicens , Kluwer Academic , Dordrecht , 2001

2. V. Böhmer , in The Chemistry of Phenols , ed. Z. Rappoport , John Wiley & Sons, Ltd , Chichester , 2003 , pp. 1369–1454

3. Calixarenes in the Nanoworld , ed. J. Vicens , J. Harrowfield and L. Baklouti , Springer , Dordrecht , 2007

4. Calixarenes and Beyond , ed. P. Neri , J. L. Sessler and M.-X. Wang , Springer International Publishing , 2016

5. Calix[4]tube: A Tobular Receptor with Remarkable Potassium Ion Selectivity

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