Palladium-catalyzed synthesis of 2,3-disubstituted indoles via arylation of ortho-alkynylanilines with arylsiloxanes

Author:

Hsia Yang-Ting1,Lu Yu-Lin1,Bai Rekha1,Badsara Satpal Singh2ORCID,Lee Chin-Fa134ORCID

Affiliation:

1. Department of Chemistry, National Chung Hsing University, Taichung, Taiwan 402, Republic of China

2. MFOS Laboratory, Department of Chemistry, University of Rajasthan, Jaipur, Rajasthan 302004, India

3. i-Center for Advanced Science and Technology (iCAST), National Chung Hsing University, Taichung City 402, Taiwan, Republic of China

4. Innovation and Development Center of Sustainable Agriculture (IDCSA), National Chung Hsing University, Taichung City 402, Taiwan, Republic of China

Abstract

A palladium-catalyzed synthesis of Larock indoles via electrophilic cyclization of N,N-dimethyl-o-alkynylanilines with arylsiloxanes in the presence of Ag2O is described.

Funder

National Chung-Hsing University

Ministry of Education

National Science and Technology Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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