Crystal structure, magnetic properties and theoretical study of a bithiazolebis(oxamate)-containing [NiII3] helicate-Reference-Cited by-同舟云学术

Crystal structure, magnetic properties and theoretical study of a bithiazolebis(oxamate)-containing [NiII3] helicate

Published:2024 Issue:5 Volume:48 Page:1971-1982
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kalinke Lucas H. G.¹^ORCID,Silva Mariany S.²,Rabelo Renato²³^ORCID,Valdo Ana K.⁴,Martins Felipe T.²,Moliner Nicolás³^ORCID,Julve Miguel³^ORCID,Lloret Francesc³^ORCID,Cano Joan³^ORCID,Cangussu Danielle²^ORCID

Affiliation:

1. Instituto Federal de Goiás, IFG-Câmpus Anápolis, Anápolis, GO, 75131-457, Brazil

2. Universidade Federal de Goiás, Instituto de Química, Goiânia, GO, 74690-900, Brazil

3. Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), C/Catedrático José Beltrán 2, 46980 Paterna (Valencia), Spain

4. Instituto Federal Goiano, IF Goiano – Campus Iporá, Iporá, GO, 76200-000, Brazil

Abstract

New trinuclear Ni(ii) complex exhibiting intratrimer both weak ferro- and antiferromagnetic interactions resulting from the strict orthogonality between the magnetic orbitals, and a combination of spin delocalisation and spin polarisation mechanisms.

Funder

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Generalitat Valenciana

Ministerio de Ciencia, Innovación y Universidades

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D3NJ04701F

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