Unveiling the mechanisms and secrets of chemoselectivities in Au(i)-catalyzed diazo-based couplings with aryl unsaturated aliphatic alcohols-Reference-Cited by-同舟云学术

Unveiling the mechanisms and secrets of chemoselectivities in Au(i)-catalyzed diazo-based couplings with aryl unsaturated aliphatic alcohols

Published:2018 Issue:17 Volume:8 Page:4450-4462
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Pei Guojing¹²³⁴,Liu Yuxia¹²³⁴^ORCID,Chen Guang¹²³⁴⁵^ORCID,Yuan Xiangai¹²³⁴,Jiang Yuan-Ye¹²³⁴^ORCID,Bi Siwei¹²³⁴^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Qufu Normal University

3. Qufu 273165

4. P. R. China

5. Institute of Functional Materials and Molecular Imaging

Abstract

The mechanisms and origins of the unsaturated-aliphatic-alcohols-modulated chemoselectivity of Au-catalyzed carbene transfers from diazo compounds are disclosed by DFT studies.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY01352G

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5. Rhodium-Catalyzed Enantioselective Vinylogous Addition of Enol Ethers to Vinyldiazoacetates

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