General CuBr2-catalyzed highly enantioselective approach for optically active allenols from terminal alkynols-Reference-Cited by-同舟云学术

General CuBr2-catalyzed highly enantioselective approach for optically active allenols from terminal alkynols

Published:2015 Issue:32 Volume:51 Page:6956-6959
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Huang Xin¹²³⁴⁵,Cao Tao⁶⁷⁸⁹¹⁰,Han Yulin⁶⁷⁸⁹¹⁰,Jiang Xingguo⁶⁷⁸⁹¹⁰,Lin Weilong⁶⁷⁸⁹¹⁰,Zhang Jiasheng⁶⁷⁸⁹¹⁰,Ma Shengming¹²³⁴⁵

Affiliation:

1. Laboratory of Molecular Recognition and Synthesis

2. Department of Chemistry

3. Zhejiang University

4. Hangzhou 310027

5. People's Republic of China

6. State Key Laboratory of Organometallic Chemistry

7. Shanghai Institute of Organic Chemistry

8. Chinese Academy of Sciences

9. Shanghai 200032

10. P. R. China

Abstract

A copper(ii) bromide-catalyzed highly enantioselective direct synthesis of 1,3-disubstituted allenols from commercially available aldehydes, terminal alkynols and (R)- or (S)-α,α-diphenylprolinol has been developed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC00697J

Reference48 articles.

1. Synthesis and Properties of Allenic Natural Products and Pharmaceuticals

2. Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses

3. Front cover

4. Allenes from Cyclopropanes and Their Use in Organic SynthesisRecent Developments

5. Synthesis of allenes with organometallic reagents

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