Cascade reactions of HDDA-benzynes with tethered cyclohexadienones: strain-driven events originating from <i>ortho</i>-annulated benzocyclobutenes-Reference-Cited by-同舟云学术

Cascade reactions of HDDA-benzynes with tethered cyclohexadienones: strain-driven events originating from ortho-annulated benzocyclobutenes

Published:2024 Issue:21 Volume:15 Page:8181-8189
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Chinta Bhavani Shankar¹,Sneddon Dorian S.¹^ORCID,Hoye Thomas R.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Minnesota, 207 Pleasant St. SE, Minneapolis, MN 55455, USA

Abstract

Reactions between a benzyne and a tethered electron-deficient alkene are explored. Depending on the length of the tether, strain-driven reaction cascades ensue that lead to a variety of mechanistically intriguing transformations.

Funder

National Science Foundation

National Institute of General Medical Sciences

National Cancer Institute

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00571F

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