Common xanthene fluorescent dyes are visible-light activatable CO-releasing molecules

Author:

Martínek Marek12,Ludvíková Lucie1,Šranková Mária3,Navrátil Rafael4,Muchová Lucie3ORCID,Huzlík Jiří5ORCID,Vítek Libor36,Klán Petr12ORCID,Šebej Peter1ORCID

Affiliation:

1. RECETOX, Faculty of Science, Masaryk University, Kamenice 735/5, D29, 625 00 Brno-Bohunice, Czech Republic

2. Department of Chemistry, Faculty of Science, Masaryk University, Kamenice 735/5, A08, 625 00 Brno-Bohunice, Czech Republic

3. Institute of Medical Biochemistry and Laboratory Diagnostics, General University Hospital in Prague and 1st Faculty of Medicine, Charles University, Kateřinská 32, 121 08 Praha 2, Czech Republic

4. Department of Organic Chemistry, Faculty of Science, Charles University, Hlavova 2030/8, 128 43, Prague, Czech Republic

5. Transport Research Centre (CDV), Líšeňská 33a, 636 00 Brno-Líšeň, Czech Republic

6. 4th Department of Internal Medicine, General University Hospital in Prague and 1st Faculty of Medicine, Charles University, Kateřinská 32, 121 08 Praha 2, Czech Republic

Abstract

Fluorescein, eosin and rose bengal, xanthene diagnostic dyes, are releasing carbon monoxide, formic and phthalic acids upon irradiation by visible light in aqueous media, previously unreported photolysis products.

Funder

Ministerstvo Dopravy

Grantová Agentura České Republiky

Grantová Agentura, Univerzita Karlova

Ministerstvo Školství, Mládeže a Tělovýchovy

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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