The influence of adsorption geometry on the reduction affinity of nitroaromatics on Au(111)-Reference-Cited by-同舟云学术

The influence of adsorption geometry on the reduction affinity of nitroaromatics on Au(111)

Published:2022 Issue:37 Volume:24 Page:22960-22970
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Berg Iris¹²,Eisenberg Helen¹³,Dery Shahar¹²,Shahar Tehila¹²,Cossaro Albano⁴^ORCID,Verdini Alberto⁴^ORCID,Floreano Luca⁴^ORCID,Stein Tamar¹³^ORCID,Gross Elad¹²^ORCID

Affiliation:

1. Institute of Chemistry, The Hebrew University, Jerusalem 91904, Israel

2. The Center for Nanoscience and Nanotechnology, The Hebrew University, Jerusalem 91904, Israel

3. The Fritz Haber Center for Molecular Dynamics Research, The Hebrew University, Jerusalem 91904, Israel

4. CNR-IOM, Laboratorio Nazionale TASC, Basovizza SS-14, Trieste 34012, Italy

Abstract

The dominant influence of adsorption geometry on chemical reactivity was identified for nitro reduction on Au(111). Reactivity was facilitated only when the nitro group was oriented in high proximity and approximately parallel to the metal surface.

Funder

H2020 European Research Council

Ministry of Energy, Israel

Azrieli Foundation

Ministry of Science, Technology and Space

Clore Israel Foundation

Center for Nanoscience and Nanotechnology, Tel Aviv University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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