Quantitative analysis of cross-talk in partly deuterated samples of nuclear spins hyperpolarized by dynamic nuclear polarization (DNP) in the thermal mixing regime-Reference-Cited by-同舟云学术

Quantitative analysis of cross-talk in partly deuterated samples of nuclear spins hyperpolarized by dynamic nuclear polarization (DNP) in the thermal mixing regime

Published:2023 Issue:21 Volume:25 Page:15040-15051
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Rodin Bogdan A.¹²³^ORCID,Thalakottoor Vineeth¹,Baudin Mathieu¹⁴,Birilirakis Nicolas¹,Bodenhausen Geoffrey¹^ORCID,Yurkovskaya Alexandra V.²³^ORCID,Abergel Daniel¹^ORCID

Affiliation:

1. Département de chimie, Laboratoire des biomolécules, LBM, Ecole normale supérieure, PSL University, Sorbonne Université, CNRS, 75005 Paris, France

2. International Tomography Center, Siberian Branch of the Russian Academy of Science, Novosibirsk 630090, Russia

3. Physics Department, Novosibirsk State University, Novosibirsk, 630090, Russia

4. Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques Université Paris Cité 145, Rue des Saints Pères 75006, Paris, France

Abstract

DNP cross-talk experiments in the thermal mixing regime provide energy transfer rates between the different reservoirs. The dependence of the kinetic parameters on the radical concentration and H/D ratio sheds light onto the nature of “hidden” spins.

Funder

Agence Nationale de la Recherche

Ministry of Education and Science of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP00453H

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