In situ observation of the on-surface thermal dehydrogenation of n-octane on Pt(111)

Author:

Arribas Daniel1ORCID,Villalobos-Vilda Víctor1,Tosi Ezequiel12,Lacovig Paolo2ORCID,Baraldi Alessandro23ORCID,Bignardi Luca2ORCID,Lizzit Silvano2,Martínez José Ignacio1ORCID,de Andres Pedro Luis14,Gutiérrez Alejandro56,Martín-Gago José Ángel1ORCID,Merino Pablo1ORCID

Affiliation:

1. Instituto de Ciencia de Materiales de Madrid, c/Sor Juana Inés de la Cruz, 3, Spain

2. Elettra-Sincrotrone Trieste S.C.p.A., S.S. 14 km 163.5, Trieste, Italy

3. Physics Department, University of Trieste, Via Valerio 2, 34127 Trieste, Italy

4. On leave of absence at nanoteeche@surfaces Laboratory, Swiss Federal Laboratories for Materials Science and Technology, 8600-Dübendorf, Switzerland

5. Applied Physics Department, Universidad Autónoma de Madrid, Calle Francisco Tomás y Valiente, 7, 28049 Madrid, Spain

6. Instituto Nicolás Cabrera, Cantoblanco, Calle Francisco Tomás y Valiente, 7, 28049 Madrid, Spain

Abstract

We study the thermal dehydrogenation of n-octane on Pt(111) under ultra-high vacuum. Combining scanning tunneling microscopy (STM), photoelectron spectroscopy and mass spectroscopy with calculations, we provide an atomic-scale view of the on-surface products.

Funder

Agencia Estatal de Investigación

Ministerio de Universidades

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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