Raman and NMR spectroscopic and theoretical investigations of the cubic laves-phases REAl2 (RE = Sc, Y, La, Yb, Lu)

Author:

Gießelmann Elias C. J.1ORCID,Engel Stefan1ORCID,Kostusiak Weronika23,Zhang Yuemei2ORCID,Herbeck-Engel Petra4,Kickelbick Guido1ORCID,Janka Oliver1ORCID

Affiliation:

1. Inorganic Solid-State Chemistry, Saarland University, Campus C4.1, 66123 Saarbrücken, Germany

2. Department of Chemistry and Physics, Warren Wilson College, Swannanoa, NC, 28778, USA

3. Department of Chemistry, University of Wroclaw, F. Joliot-Curie 14, 50-383 Wroclaw, Poland

4. INM Leibniz Institute for New Materials, Campus D2.2, 66123 Saarbrücken, Germany

Abstract

The REAl2 series was characterized by solid-state NMR and Raman experiments. The spectroscopic data was correlated to the XRD measurements and the DFT calculations, gaining an insight into bonding, charge distribution and the strain.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference67 articles.

1. O.Janka , Metallic light-weight alloys: Al, Ti, Mg , in Applied Inorganic Chemistry , ed. R. Pöttgen , T. Jüstel and C. Strassert , De Gruyter , 2022 , pp. 158–173

2. F.Ostermann , Anwendungstechnologie Aluminium , Springer Vieweg , Berlin, Heidelberg , 2014

3. Structure Refinement of S-Phase Precipitates in Al-Cu-Mg Alloys by Quantitative HRTEM

4. Structure Refinement of the S-Phase Precipitate MgCuAl2

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