Electrochemical desulfurative formation of C–N bonds through selective activation of inert C(sp<sup>3</sup>)

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Electrochemical desulfurative formation of C–N bonds through selective activation of inert C(sp³)–S bonds

Published:2024 Issue:18 Volume:60 Page:2501-2504
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Guo Shaopeng¹,Li Yujun¹,Li Qing-Han²,Zheng Ke¹^ORCID

Affiliation:

1. Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, 610064, P. R. China

2. Key Laboratory of General Chemistry of the National Ethnic Affairs Commission, College of Chemistry and Environment, Southwest Minzu University, Chengdu, PR China

Abstract

An efficient, metal-free electrocatalytic desulfurative strategy for the construction of C–N bonds by selectively activating inert C(sp3)–S bonds of alkyl thioethers.

Funder

Sichuan University

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00142G

Reference43 articles.

1. Construction of sulfur-containing moieties in the total synthesis of natural products

2. Prospects and Challenges in Organosulfur Chemistry

3. Desulfonylative Transformations of Sulfones by Transition-Metal Catalysis, Photocatalysis, and Organocatalysis

4. Transition Metal‐Catalyzed Cross‐Couplings of Benzylic Sulfone Derivatives

5. Transition-metal mediated carbon–sulfur bond activation and transformations: an update

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