The electronic properties of three popular high spin complexes [TM(acac)3, TM = Cr, Mn, and Fe] revisited: an experimental and theoretical study-Reference-Cited by-同舟云学术

The electronic properties of three popular high spin complexes [TM(acac)3, TM = Cr, Mn, and Fe] revisited: an experimental and theoretical study

Published:2017 Issue:36 Volume:19 Page:24840-24854
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Carlotto S.¹²³⁴,Floreano L.⁵⁶⁷⁴^ORCID,Cossaro A.⁵⁶⁷⁴^ORCID,Dominguez M.⁵⁶⁷⁴⁸,Rancan M.⁹³⁴,Sambi M.¹²³⁴,Casarin M.¹²³⁴⁹^ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche

2. Università degli Studi di Padova

3. I-35131 Padova

4. Italy

5. CNR-IOM

6. Laboratorio TASC

7. I-34149 Trieste

8. Dipartimento di Fisica

9. Istituto di Chimica della Materia Condensata e di Tecnologie per l'Energia – ICMATE

Abstract

The combined use of NEXAFS spectroscopic data and DFT results on TM(acac)₃(TM = Cr, Mn, Fe) allowed us to look into the TM–ligand bonding scheme and to rationalize the peculiar electronic and structural properties of the title complexes.

Funder

Università degli Studi di Padova

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP04461E

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