Ni-Catalyzed asymmetric reduction of α-keto-β-lactams via DKR enabled by proton shuttling-Reference-Cited by-同舟云学术

Ni-Catalyzed asymmetric reduction of α-keto-β-lactams via DKR enabled by proton shuttling

Published:2020 Issue:99 Volume:56 Page:15557-15560
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Fangyuan¹²³⁴⁵,Tan Xuefeng⁵⁶⁷⁸⁹,Wu Ting¹⁰⁷⁸⁹,Zheng Long-Sheng⁵⁶⁷⁸⁹,Chen Gen-Qiang¹¹⁷¹²⁴^ORCID,Zhang Xumu⁵⁶⁷⁸⁹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Harbin Institute of Technology

3. Harbin 150001

4. People's Republic of China

5. Shenzhen Grubbs Institute and Department of Chemistry

6. Guangdong Provincial Key Laboratory of Catalysis

7. Southern University of Science and Technology

8. Shenzhen

9. China

10. College of Innovation and Entrepreneurship

11. Academy for Advanced Interdisciplinary Studies

12. Shenzhen 518000

Abstract

A wide range of α-keto-β-lactams were reduced efficiently and enantioselectively by Ni-catalyzed asymmetric hydrogenation. Phenylphosphinic acid was found to play a pivotal role in the DKR of α-keto-β-lactams by promoting the enolization process.

Funder

National Natural Science Foundation of China

Southern University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC05599A

Reference72 articles.

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5. B. K. Banik , β-Lactams: Unique Structures of Distinction for Novel Molecules , Topics in Heterocyclic Chemistry , Springer GmbH , 2013 , vol. 30

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